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N,O-Bis(trimethylsilyl)trifluoroacetamide - for GC derivatization, ≥98.0%, high purity , CAS No.25561-30-2

41 Citations

for GC derivatization

≥98%(GC)

CAS#: 25561-30-2
Molecular Weight: 257.4
Beilstein Registry Number: 2050024
EC Number: 247-103-9
MDL number: MFCD00008269
PubChem CID: 94358

In stock

Item Number

B118472

Grouped product items
SKU	Size	Availability	Price
B118472-1ml	1ml	1	$33.90
B118472-5ml	5ml	3	$75.90
B118472-10×1ml	10×1ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$314.90
B118472-25ml	25ml	1	$188.90
B118472-100ml	100ml	1	$459.90

View related series

Silicon compound (537) Trifluoroacetamides (1)

Basic Description

Synonyms	NSC 379423 \| Q1281115 \| (3S)-5-fluoro-3-[[(2S)-2-[[(2S)-3-methyl-2-(phenylmethoxycarbonylamino)butanoyl]amino]propanoyl]amino]-4-oxopentanoic acid \| N-trimethylsilyl-trifluoroacetylimidic acid trimethylsilyl ester \| Trimethylsilyl (1Z)-2,2,2-trifluoro-N-[
Specifications & Purity	for GC derivatization, ≥98%(GC)
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice
Grade	for GC derivatization
Product Description	N,O-Bis(trimethylsilyl)trifluoroacetamide is an organosilicon reagent for trimethylsilylation, deprotection, dehydrogenation, allylic alkylation, nitronate formation, and Claisen rearrangement. BSTFA is a silylating agent used in the synthesis of 4-Quinolones.

Names and Identifiers

IUPAC Name	trimethylsilyl 2,2,2-trifluoro-N-trimethylsilylethanimidate
INCHI	InChI=1S/C8H18F3NOSi2/c1-14(2,3)12-7(8(9,10)11)13-15(4,5)6/h1-6H3
InChi Key	XCOBLONWWXQEBS-UHFFFAOYSA-N
Canonical SMILES	C[Si](C)(C)N=C(C(F)(F)F)O[Si](C)(C)C
Isomeric SMILES	C[Si](C)(C)N=C(C(F)(F)F)O[Si](C)(C)C
WGK Germany	3
Alternate CAS	152571-61-4
UN Number	2924
Molecular Weight	257.4
Beilstein	2050024
Reaxy-Rn	3607620
Reaxys-RN_link_address	https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3607620&ln=

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):

Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

27 results found

Lot Number	Certificate Type	Date	Item
G2320346	Certificate of Analysis	Apr 18, 2025	B118472
G2320350	Certificate of Analysis	Apr 09, 2025	B118472
A2508291	Certificate of Analysis	Dec 14, 2024	B118472
A2508292	Certificate of Analysis	Dec 14, 2024	B118472
A2508289	Certificate of Analysis	Dec 14, 2024	B118472
A2508290	Certificate of Analysis	Dec 14, 2024	B118472
I2407025	Certificate of Analysis	Aug 29, 2024	B118472
I2407029	Certificate of Analysis	Aug 29, 2024	B118472
L2402031	Certificate of Analysis	Aug 29, 2024	B118472
I2407032	Certificate of Analysis	Aug 29, 2024	B118472
I2407042	Certificate of Analysis	Aug 29, 2024	B118472
E2417109	Certificate of Analysis	May 09, 2024	B118472
E2417110	Certificate of Analysis	May 09, 2024	B118472
E2417107	Certificate of Analysis	May 09, 2024	B118472
E2417108	Certificate of Analysis	May 09, 2024	B118472
E2417111	Certificate of Analysis	May 09, 2024	B118472
C2414174	Certificate of Analysis	Nov 18, 2023	B118472
C2414209	Certificate of Analysis	Nov 18, 2023	B118472
C2414207	Certificate of Analysis	Nov 18, 2023	B118472
C2414208	Certificate of Analysis	Nov 18, 2023	B118472
G2320354	Certificate of Analysis	Jul 14, 2023	B118472
G2320361	Certificate of Analysis	Jul 14, 2023	B118472
G2206102	Certificate of Analysis	Jun 28, 2022	B118472
G2206065	Certificate of Analysis	Jun 28, 2022	B118472
G2206100	Certificate of Analysis	Jun 28, 2022	B118472
G2206064	Certificate of Analysis	Jun 28, 2022	B118472
A2219167	Certificate of Analysis	Jan 27, 2022	B118472

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Chemical and Physical Properties

Solubility	Miscible with chloroform.
Sensitivity	Heat & Moisture Sensitive
Refractive Index	1.384
Flash Point(°F)	42.8 °F
Flash Point(°C)	24 °C
Boil Point(°C)	142°C
Melt Point(°C)	-41°C(lit.)
Molecular Weight	257.399 g/mol
XLogP3
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	5
Rotatable Bond Count	3
Exact Mass	257.088 Da
Monoisotopic Mass	257.088 Da
Topological Polar Surface Area	21.600 Å²
Heavy Atom Count	15
Formal Charge	0
Complexity	250.000
Isotope Atom Count	0
Defined Atom Stereocenter Count	0
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	0
Undefined Bond Stereocenter Count	1
The total count of all stereochemical bonds	1
Covalently-Bonded Unit Count	1

Safety and Hazards(GHS)

Pictogram(s)	GHS07, GHS02
Signal	Warning
Hazard Statements	H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation H314:Causes severe skin burns and eye damage H225:Highly Flammable liquid and vapor H226:Flammable liquid and vapor
Precautionary Statements	P261:Avoid breathing dust/fume/gas/mist/vapors/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use ... to extinguish. P210:Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking. P302+P352:IF ON SKIN: wash with plenty of water. P321:Specific treatment (see ... on this label). P405:Store locked up. P501:Dispose of contents/container to ... P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P264:Wash hands [and …] thoroughly after handling. P403+P235:Store in a well-ventilated place. Keep cool. P260:Do not breathe dust/fume/gas/mist/vapors/spray. P303+P361+P353:IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower]. P271:Use only outdoors or in a well-ventilated area. P241:Use explosion-proof [electrical/ventilating/lighting/.../] equipment. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340:IF INHALED: Remove person to fresh air and keep comfortable for breathing. P363:Wash contaminated clothing before reuse. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P362+P364:Take off contaminated clothing and wash it before reuse. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P264+P265:Wash hands [and …] thoroughly after handling. Do not touch eyes. P305+P354+P338:IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P337+P317:If eye irritation persists: Get medical help. P332+P317:If skin irritation occurs: Get medical help. P302+P361+P354:IF ON SKIN: Take off Immediately all contaminated clothing. Immediately rinse with water for several minutes. P316:Get emergency medical help immediately. P319:Get medical help if you feel unwell.
WGK Germany	3
Reaxy-Rn	3607620
Reaxys-RN_link_address	https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3607620&ln=

Specifications

Purity(GC)	98-100（%）
Appearance（B118472)	Clear colorless to pale yellow Liquid
GC derivatization test	pass
Infrared spectrum	Conforms to Structure
Proton NMR spectrum	Conforms to Structure

Specification Sheet

Alternative Products

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Yunping Yao, Tianliang Wang, Zhiyuan Qiang, Wenqi Du, Changmo Li. (2024) Mechanisms of the Formation of Nonvolatile and Volatile Oxidation Products from Methyl Linoleic Acid at High Temperatures. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 72 (1): (704–714). [PMID:38131267] [10.1021/acs.jafc.3c04405]
2. Ziyan Wang, Zhixuan Zhang, Qiuyue Shi, Songyi Liu, Qiaoli Wu, Ze Wang, Emilaguli Saiding, Jiaojiao Han, Jun Zhou, Rixin Wang, Xiurong Su. (2023) Comparison of Lactiplantibacillus plantarum isolates from the gut of mice supplemented with different types of nutrients: a genomic and metabolomic study. Frontiers in Microbiology, 14 (12): (1295058). [PMID:38033563] [10.3389/fmicb.2023.1295058]
3. Guangxu Yang, Zhenggang Gong, Bei Zhou, Xiaolin Luo, Jing Liu, Guanben Du, Chengke Zhao, Li Shuai. (2023) Hydrodeoxygenation of condensed lignins followed by acid-mediated methylolation enables preparation of lignin-based wood adhesives. GREEN CHEMISTRY, [PMID:8723681] [10.1039/D3GC03935H]
4. Haoran Zhou, Luan Wen, Liwu Lin, Zhongrong Li, Minghua Qiu. (2023) Refined waxy product from the residues of pyrethrins processing: contents, compositions and skin-whitening effects. INDUSTRIAL CROPS AND PRODUCTS, 206 (117564). [PMID:19583955] [10.1016/j.indcrop.2023.117564]
5. Yang Guangxu, Gong Zhenggang, Luo Xiaolin, Chen Lihui, Shuai Li. (2023) Bonding wood with uncondensed lignins as adhesives. NATURE, 621 (7979): (511-515). [PMID:37553075] [10.1038/s41586-023-06507-5]
6. Jing Bai, Hao Li, Yuting Zhu, Yiping Zhu, Chenguang Wang, Haiyong Wang, Yuhe Liao. (2023) Synthesis of 2,6-Dimethoxy-p-aminophenol from Hardwood Lignin. ChemSusChem, (e202300558). [PMID:37449540] [10.1002/cssc.202300558]
7. Jingshun Zhuang, Saerona Kim, Mairui Zhang, Jiae Ryu, Jeeranan Nonkumwong, Laongnuan Srisombat, Kwang Ho Kim, Jeong Jae Wie, Gyu Leem, Chang Geun Yoo. (2023) MgFe2O4 Nanoparticle/Peracetic Acid Hybrids for Catalytic Oxidative Depolymerization of Lignin. ACS Applied Nano Materials, 6 (12): (10758–10767). [PMID:] [10.1021/acsanm.3c01910]
8. Hua Xu, Yandan Wang, Yiren Zhang, Qiaoming Lou, Xiupeng Guan, Jun Jin, Qingzhe Jin, Xingguo Wang. (2023) Characteristics of Cephalotaxus fortunei kernel oil and its digestion behaviors. FOOD CHEMISTRY, 426 (136466). [PMID:37352711] [10.1016/j.foodchem.2023.136466]
9. Zewen Pan, Rui Wang, Jun Wei, Yingjie Cao. (2023) Development and Application of a Purification Method for the Determination of Three EDCs Isotopes in Sediments and Water. Sustainability, 15 (11): (8583). [PMID:] [10.3390/su15118583]
10. Qingwen Zhu, Yujing Yang, Zheling Zeng, Ting Peng, Xianghui Yan, Junxin Zhao, Jiaheng Xia, Ping Yu, Xuefang Wen, Deming Gong. (2023) Effect of processing method on chemical composition, physicochemical property, antioxidant activity and volatile compound of Cinnamomum camphora seed kernel oil. INDUSTRIAL CROPS AND PRODUCTS, 201 (116907). [PMID:] [10.1016/j.indcrop.2023.116907]
11. Lilai Mo, Xinzhuan Yao, Hu Tang, Yan Li, Yujie Jiao, Yumei He, Yihe Jiang, Shiyu Tian, Litang Lu. (2023) Genome-Wide Investigation and Functional Analysis Reveal That CsKCS3 and CsKCS18 Are Required for Tea Cuticle Wax Formation. Foods, 12 (10): (2011). [PMID:37238828] [10.3390/foods12102011]
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15. Ziru Li, Xia Yuan, Huili Tang, Xu Jiang, Chunge Wu, Lu Zheng, Erdeng Du, Mingguo Peng. (2022) Experimental study and quantum chemical calculation of free radical reactions in ciprofloxacin degradation during the UV/chlorine oxidation process. Environmental Science-Water Research & Technology, 8 (11): (2744-2760). [PMID:] [10.1039/D2EW00320A]
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19. Xiaoya Tao, Qiong Wu, Suqing Huang, Beiwei Zhu, Feng Chen, Bin Liu, Luyun Cai, Linchun Mao, Zisheng Luo, Li Li, Tiejin Ying. (2022) Exogenous abscisic acid regulates primary metabolism in postharvest cherry tomato fruit during ripening. SCIENTIA HORTICULTURAE, 299 (111008). [PMID:] [10.1016/j.scienta.2022.111008]
20. Hanxiao Zhou, Huimin Shang, Tianhui Li, Wenjing Liu, Zhihao Guo, Yuxuan Guo, Jingjing Gao, Meizhen Qu, Huan Zhang, Gongchang Peng. (2022) N,O-Bis(trimethylsilyl)trifluoroacetamide as an Effective Interface Film Additive on Lithium Anodes. ACS Applied Materials & Interfaces, 14 (4): (5447–5458). [PMID:35045247] [10.1021/acsami.1c22604]
21. Yue Gao, Fang Yang, Hongxian Jian, Kai Zhen, Peng Zhang, Xuejiao Tang, Zhen Fu, Wei Xu, Cuiping Wang, Hongwen Sun. (2021) Pyrene degradation in an aqueous system using ferrous citrate complex activated persulfate over a wide pH range. Journal of Environmental Chemical Engineering, 9 (106733). [PMID:] [10.1016/j.jece.2021.106733]
22. Xingqi Huang, Ting Zhao, Hongpeng Zhang, Chunxiao Yan, Jiulong Sha, Huamin Tang, Haiyan Zhu, Yue Wu. (2021) Dual-purpose high-efficiency air filter paper loaded with reactive zirconium hydroxide for the filtration aerosols and degradation of chemical warfare agents. RSC Advances, 11 (56): (35245-35257). [PMID:35493143] [10.1039/D1RA06903A]
23. Yu Feng, Ao Wang, Wenxian Fu, Donghui Song. (2022) Growth performance, antioxidant response, biodegradation and transcriptome analysis of Chlorella pyrenoidosa after nonylphenol exposure. SCIENCE OF THE TOTAL ENVIRONMENT, 806 (150507). [PMID:34583075] [10.1016/j.scitotenv.2021.150507]
24. Rui Tang, Xue-Hong Qiu, Li Cao, Hai-Lin Long, Ri-Chou Han. (2021) Stage- and Rearing-Dependent Metabolomics Profiling of Ophiocordyceps sinensis and Its Pipeline Products. Insects, 12 (8): (666). [PMID:34442232] [10.3390/insects12080666]
25. Chuan Zhang, Liwen Cui, Peian Zhang, Tianyu Dong, Jinggui Fang. (2021) Transcriptome and metabolite profiling reveal that spraying calcium fertilizer reduces grape berry cracking by modulating the flavonoid biosynthetic metabolic pathway. Food Chemistry: Molecular Sciences, 2 (100025). [PMID:35415636] [10.1016/j.fochms.2021.100025]
26. Wenjiang Dong, Qiyu Chen, Changqing Wei, Rongsuo Hu, Yuzhou Long, Ying Zong, Zhong Chu. (2021) Comparison of the effect of extraction methods on the quality of green coffee oil from Arabica coffee beans: Lipid yield, fatty acid composition, bioactive components, and antioxidant activity. ULTRASONICS SONOCHEMISTRY, 74 (105578). [PMID:33965776] [10.1016/j.ultsonch.2021.105578]
27. Cong Zi-Xiang, Shao Xue-Ting, Liu Si-Yu, Pei Wei, Wang De-Gao. (2021) Wastewater analysis reveals urban, suburban, and rural spatial patterns of illicit drug use in Dalian, China. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 28 (20): (25503-25513). [PMID:33459987] [10.1007/s11356-021-12371-5]
28. Hongtu Qiu, Zhuangzhuang Qiu, Zhiyu Chen, Longlong Liu, Jiabin Wang, Hongyu Jiang, Hua Zhang, Guo-qin Liu. (2021) Antioxidant properties of blueberry extract in different oleogel systems. LWT-FOOD SCIENCE AND TECHNOLOGY, 137 (110364). [PMID:] [10.1016/j.lwt.2020.110364]
29. Yifeng Chai, Ang Li, Su Chit Wai, Congcong Song, Yaoyao Zhao, Yuquan Duan, Baiqing Zhang, Qiong Lin. (2020) Cuticular wax composition changes of 10 apple cultivars during postharvest storage. FOOD CHEMISTRY, 324 (126903). [PMID:32361095] [10.1016/j.foodchem.2020.126903]
30. You Zhou, De-Qiang Qin, Pei-Wen Zhang, Ben-Ju Liu, Xiao-Tian Chen, Zhi-Xiang Zhang. (2020) The comparative metabolic response of Bactrocera dorsalis larvae to azadirachtin, pyriproxyfen and tebufenozide. ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 189 (110020). [PMID:31809954] [10.1016/j.ecoenv.2019.110020]
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41. Yimeng Zhou,Ning Li,Zhixia Qiu,Xiaoyu Lu,Min Fang,Xijing Chen,Lili Ren,Guangji Wang,Pingkai Ouyang. (2018-07-20) Superior anti-neoplastic activities of triacontanol-PEG conjugate: synthesis, characterization and biological evaluations.. Drug delivery, 25 ((1)): (1546-1559). [PMID:30022695]
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References

1. Yunping Yao, Tianliang Wang, Zhiyuan Qiang, Wenqi Du, Changmo Li. (2024) Mechanisms of the Formation of Nonvolatile and Volatile Oxidation Products from Methyl Linoleic Acid at High Temperatures. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 72 (1): (704–714). [PMID:38131267] [10.1021/acs.jafc.3c04405]
2. Ziyan Wang, Zhixuan Zhang, Qiuyue Shi, Songyi Liu, Qiaoli Wu, Ze Wang, Emilaguli Saiding, Jiaojiao Han, Jun Zhou, Rixin Wang, Xiurong Su. (2023) Comparison of Lactiplantibacillus plantarum isolates from the gut of mice supplemented with different types of nutrients: a genomic and metabolomic study. Frontiers in Microbiology, 14 (12): (1295058). [PMID:38033563] [10.3389/fmicb.2023.1295058]
3. Guangxu Yang, Zhenggang Gong, Bei Zhou, Xiaolin Luo, Jing Liu, Guanben Du, Chengke Zhao, Li Shuai. (2023) Hydrodeoxygenation of condensed lignins followed by acid-mediated methylolation enables preparation of lignin-based wood adhesives. GREEN CHEMISTRY, [PMID:8723681] [10.1039/D3GC03935H]
4. Haoran Zhou, Luan Wen, Liwu Lin, Zhongrong Li, Minghua Qiu. (2023) Refined waxy product from the residues of pyrethrins processing: contents, compositions and skin-whitening effects. INDUSTRIAL CROPS AND PRODUCTS, 206 (117564). [PMID:19583955] [10.1016/j.indcrop.2023.117564]
5. Yang Guangxu, Gong Zhenggang, Luo Xiaolin, Chen Lihui, Shuai Li. (2023) Bonding wood with uncondensed lignins as adhesives. NATURE, 621 (7979): (511-515). [PMID:37553075] [10.1038/s41586-023-06507-5]
6. Jing Bai, Hao Li, Yuting Zhu, Yiping Zhu, Chenguang Wang, Haiyong Wang, Yuhe Liao. (2023) Synthesis of 2,6-Dimethoxy-p-aminophenol from Hardwood Lignin. ChemSusChem, (e202300558). [PMID:37449540] [10.1002/cssc.202300558]
7. Jingshun Zhuang, Saerona Kim, Mairui Zhang, Jiae Ryu, Jeeranan Nonkumwong, Laongnuan Srisombat, Kwang Ho Kim, Jeong Jae Wie, Gyu Leem, Chang Geun Yoo. (2023) MgFe2O4 Nanoparticle/Peracetic Acid Hybrids for Catalytic Oxidative Depolymerization of Lignin. ACS Applied Nano Materials, 6 (12): (10758–10767). [PMID:] [10.1021/acsanm.3c01910]
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